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Crystal structure of 1-[(4-methylphenyl)sulfonyl]-2-phenylazetidine

Berthy J. Aroche, Katherine Barraza Hernandez, Zoe Y. Marr, S. Chantal E. Stieber, Taylor A. Thane

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Source: Crossref

Published: Oct 11, 2026

DOI: 10.1107/s2056989026010315

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Source abstract

The crystal structure of 1-[(4-methylphenyl)sulfonyl]-2-phenylazetidine, C 16 H 17 NO 2 S, commonly referred to as 2-phenyl- N -tosylazetidine, is reported. There are three close contacts stabilizing the supramolecular structure. Two of the close contacts are between one of the O atoms on the sulfonamide moiety and two neighboring C—H bonds from the tolyl ring. The third close contact is between the H—C bond of the azetidine and a C atom on the phenyl ring. Distances between the tolyl rings are greater than the standard distance of 5 Å for π-stacking.

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