Note on the contact between a metal and an insulator or semi-conductor

Source abstract

According to quantum mechanics there exists in any non-metallic crystal a band of allowed electronic energy levels which are unoccupied when the crystal is in its state of lowest energy. We call this band the conduction band; the crystal can conduct electricity if electrons are raised into the conduction level from lower levels. According to the theory of semi-conductors given by Wilson, there exist in these substances lattice imperfections at which an electron can exist in a bound stationary state below the conduction band, electrons being raised from these levels into the conduction band by the thermal agitation of the surrounding atoms.