One-dimensional hydrogen atom
Rodney Loudon
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Source: Crossref
Published: Jan 1, 2016
DOI: 10.1098/rspa.2015.0534
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The theory of the one-dimensional (1D) hydrogen atom was initiated by a 1952 paper but, after more than 60 years, it remains a topic of debate and controversy. The aim here is a critique of the current status of the theory and its relation to relevant experiments. A 1959 solution of the Schrödinger equation by the use of a cut-off at x = a to remove the singularity at the origin in the 1/| x | form of the potential is clarified and a mistaken approximation is identified. The singular atom is not found in the real world but the theory with cut-off has been applied successfully to a range of four practical three-dimensional systems confined towards one dimension, particularly their observed large increases in ground state binding energy. The true 1D atom is in principle restored when the short distance a tends to zero but it is sometimes claimed that the solutions obtained by the limiting procedure differ from those obtained by solution of the basic Schrödinger equation without any cut-off in the potential. The treatment of the singularity by a limiting procedure for applications to practical systems is endorsed.
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