Advances in Mathematical Modeling of Gas-Phase Olefin Polymerization
Mohd Farid Atan, Mohd Azlan Hussain, Mohammad Reza Abbasi, Mohammad Jakir Hossain Khan, Muhamad Fazly Abdul Patah
Source abstract
Mathematical modeling of olefin polymerization processes has advanced significantly, driven by factors such as the need for higher-quality end products and more environmentally-friendly processes. The modeling studies have had a wide scope, from reactant and catalyst characterization and polymer synthesis to model validation with plant data. This article reviews mathematical models developed for olefin polymerization processes. Coordination and free-radical mechanisms occurring in different types of reactors, such as fluidized bed reactor (FBR), horizontal-stirred-bed reactor (HSBR), vertical-stirred-bed reactor (VSBR), and tubular reactor are reviewed. A guideline for the development of mathematical models of gas-phase olefin polymerization processes is presented.
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