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Inorganic Molybdenum Clusters as Light‐Harvester in All Inorganic Solar Cells: A Proof of Concept

Adèle Renaud, Fabien Grasset, Benjamin Dierre, Tetsuo Uchikoshi, Naoki Ohashi, Toshiaki Takei, Aurélien Planchat, Laurent Cario, Stéphane Jobic, Fabrice Odobel, Stéphane Cordier

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Source: Crossref

Published: Jul 1, 2016

DOI: 10.1002/slct.201600508

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Source abstract

Abstract The first step of the integration of molybdenum clusters as new absorbers in all inorganic solar cells inspired from perovskite cells have been investigated via the fabrication of first cluster sensitized solar cells. The latter have been realized from the photoelectrodes obtained by chemisorption of the clusters on TiO 2 and NiO films (respectively named photoanodes and photocathodes). Photovoltaic characteristics reveal that photoinduced electron or hole transfers can occur from the cluster units to the n‐ or p‐type semiconductors respectively. These first photovoltaic performances highlight the interest in using this inorganic cluster as new absorber for photo‐electronical systems.

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