mathematical-physics / Many-body quantum mechanics; Coulomb systems

The ionization conjecture: bounded excess charge, ionization energy and radius for Coulomb atoms and molecules (Simon's Problem 9)

Theorem 1.1: there is a universal CC such that for every M≥1M\ge1, all distinct nuclear positions and all real charges zj≥1z_j\ge1 with Z=∑zjZ=\sum z_j, strict binding En<En−1E_n<E_{n-1} implies n≤Z+CMn\le Z+CM, and En=En−1E_n=E_{n-1} for n>Z+CMn>Z+CM. For atoms this is Simon's bounded excess charge. Theorem 1.2: for every integer Z≥1Z\ge1 and every neutral ground state, the radius outside which half an electron remains lies between universal constants. Corollary 1.3: the neutral first ionization energy satisfies c≤I1(Z)≤Cc\le I_1(Z)\le C. Not shown: the value of the constants, relativistic or magnetic models, or the asymptotic (generalized) form, which is the separate generalized ionization entry.

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mathematical-physicsSep 24, 2026Significance 55/100Registry: unreviewed

The ionization conjecture: bounded excess charge, ionization energy and radius for Coulomb atoms and molecules (Simon's Problem 9)

Prior state unknown→proved

Theorem 1.1: there is a universal CC such that for every M≥1M\ge1, all distinct nuclear positions and all real charges zj≥1z_j\ge1 with Z=∑zjZ=\sum z_j, strict binding En<En−1E_n<E_{n-1} implies n≤Z+CMn\le Z+CM, and En=En−1E_n=E_{n-1} for n>Z+CMn>Z+CM. For atoms this is Simon's bounded excess charge. Theorem 1.2: for every integer Z≥1Z\ge1 and every neutral ground state, the radius outside which half an electron remains lies between univer…

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Theorem 1.1: there is a universal CC such that for every M≥1M\ge1, all distinct nuclear positions and all real charges zj≥1z_j\ge1 with Z=∑zjZ=\sum z_j, strict binding En<En−1E_n<E_{n-1} implies n≤Z+CMn\le Z+CM, and En=En−1E_n=E_{n-1} for n>Z+CMn>Z+CM. For atoms this is Simon's bounded excess charge. Theorem 1.2: for every integer Z≥1Z\ge1 and every neutral ground state, the radius outside which half an electron remains lies between universal constants. Corollary 1.3: the neutral first ionization energy satisfies c≤I1(Z)≤Cc\le I_1(Z)\le C. Not shown: the value of the constants, relativistic or magnetic models, or the asymptotic (generalized) form, which is the separate generalized ionization entry.

Theorem 1.1: there is a universal CC such that for every M≥1M\ge1, all distinct nuclear positions and all real charges zj≥1z_j\ge1 with Z=∑zjZ=\sum z_j, strict binding En<En−1E_n<E_{n-1} implies n≤Z+CMn\le Z+CM, and En=En−1E_n=E_{n-1} for n>Z+CMn>Z+CM. For atoms this is Simon's bounded excess charge. Theorem 1.2: for every integer Z≥1Z\ge1 and every neutral ground state, the radius outside which half an electron remains lies between universal constants. Corollary 1.3: the neutral first ionization energy satisfies c≤I1(Z)≤Cc\le I_1(Z)\le C. Not shown: the value of the constants, relativistic or magnetic models, or the asymptotic (generalized) form, which is the separate generalized ionization entry.

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The ionization conjecture: bounded excess charge, ionization energy and radius for Coulomb atoms and molecules (Simon's Problem 9) — Mathematical Frontier Network