Problems / mathematical-physics
mathematical-physics / Many-body quantum mechanics; Coulomb systems
The ionization conjecture: bounded excess charge, ionization energy and radius for Coulomb atoms and molecules (Simon's Problem 9)
Theorem 1.1: there is a universal C such that for every M≥1, all distinct nuclear positions and all real charges zj≥1 with Z=∑zj, strict binding En<En−1 implies n≤Z+CM, and En=En−1 for n>Z+CM. For atoms this is Simon's bounded excess charge. Theorem 1.2: for every integer Z≥1 and every neutral ground state, the radius outside which half an electron remains lies between universal constants. Corollary 1.3: the neutral first ionization energy satisfies c≤I1(Z)≤C. Not shown: the value of the constants, relativistic or magnetic models, or the asymptotic (generalized) form, which is the separate generalized ionization entry.